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Accessibility information
Author(s):   Shi, B.; Ji, Y.; Dabbagh, A.; Davis, B.H.
Title:   Pyrolysis of alkyl acetates. A radical pathway for the formation of minor products
Journal:   J. Org. Chem.
Volume:   59
Page(s):   845 - 849
Year:   1994
Reference type:   Journal article
Squib:   1994SHI/JI845-849

Reaction:   Acetic acid, decyl ester → Products
Reaction order:   1
Temperature:   623 - 768 K
Rate expression:   3.11x1011 [s-1] e-183750 [J/mole]/RT
Bath gas:   Acetic acid, decyl ester
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
623 1.22E-4
625 1.37E-4
650 5.33E-4
675 1.88E-3
700 6.05E-3
725 1.80E-2
750 4.96E-2
768 9.90E-2