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Accessibility information
Author(s):   Shu, Y.; Atkinson, R.
Title:   Rate constants for the gas-phase reactions of O3 with a series of terpenes and OH radical formation from the O3 reactions with sesquiterpenes at 296 ± 2 K
Journal:   Int. J. Chem. Kinet.
Volume:   26
Page(s):   1193 - 1205
Year:   1994
Reference type:   Journal article
Squib:   1994SHU/ATK1193-1205

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1994SHU/ATK1193-1205   Caryophyllene + O3 → Products  296   9.98              2
  Reference reaction:  (CH3)2C=C(CH3)2 + O3 → Products 2
  1994SHU/ATK1193-1205   Caryophyllene + O3 → Products  296   1.16E-14              2
  1994SHU/ATK1193-1205   α-Terpinene + O3 → Products  296   2.11E-14              2
  1994SHU/ATK1193-1205   α-Terpinene + O3 → Products  296   1.82              2
  Reference reaction:  Caryophyllene + O3 → Products 2
  1994SHU/ATK1193-1205   α-Cedrene + O3 → Products  296   2.77E-17              2
  1994SHU/ATK1193-1205   α-Cedrene + O3 → Products  296   0.23              2
  Reference reaction:  (Z)-2-C4H8 + O3 → Products 2
  1994SHU/ATK1193-1205   Longifolene + O3 → Products  296   <7.01E-18              2
  1994SHU/ATK1193-1205   Longifolene + O3 → Products  296   <0.05              2
  Reference reaction:  (Z)-2-C4H8 + O3 → Products 2
  1994SHU/ATK1193-1205   Terpinolene + O3 → Products  296   1.88E-15              2
  1994SHU/ATK1193-1205   Terpinolene + O3 → Products  296   1.68              2
  Reference reaction:  (CH3)2C=C(CH3)2 + O3 → Products 2
  1994SHU/ATK1193-1205   Copaene + O3 → Products  296   1.58E-16              2
  1994SHU/ATK1193-1205   Copaene + O3 → Products  296   0.38              2
  Reference reaction:  (CH3)2C=CHCH3 + O3 → Products 2
  1994SHU/ATK1193-1205   α-Phellandrene (R) + O3 → Products  296   2.97E-15              2
  1994SHU/ATK1193-1205   α-Phellandrene (R) + O3 → Products  296   2.66              2
  Reference reaction:  (CH3)2C=C(CH3)2 + O3 → Products 2
  1994SHU/ATK1193-1205   d-Limonene + O3 → Products  296   2.01E-16              2
  1994SHU/ATK1193-1205   d-Limonene + O3 → Products  296   1.65              2
  Reference reaction:  (Z)-2-C4H8 + O3 → Products 2
  1994SHU/ATK1193-1205   Humulene + O3 → Products  296   1.17E-14              2
  1994SHU/ATK1193-1205   Humulene + O3 → Products  296   10.30              2
  Reference reaction:  (CH3)2C=C(CH3)2 + O3 → Products 2

Search returned 18 records.