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Author(s):   Zabel, F.; Kirchner, F.; Becker, K.H.
Title:   Thermal decomposition of CF3C(O)O2NO2, CClF2C(O)O2NO2, CCl2FC(O)O2NO2, and CCl3C(O)O2NO2
Journal:   Int. J. Chem. Kinet.
Volume:   26
Page(s):   827 - 845
Year:   1994
Reference type:   Journal article
Squib:   1994ZAB/KIR827-845

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1994ZAB/KIR827-845   CF3C(O)O2NO2 → NO2 + CF3C(O)OO(·)  313 - 321   1.10E17       1.20E05      1
  1994ZAB/KIR827-845   CF3C(O)O2NO2 → NO2 + CF3C(O)OO(·)  313 - 321   6.00E16       1.19E05      1
  1994ZAB/KIR827-845   CF3C(O)O2NO2 → NO2 + CF3C(O)OO(·)  313 - 321   0.04       1.03E05      2
  1994ZAB/KIR827-845   CClF2C(O)OONO2 → CClF2C(O)OO· + NO2  313 - 322   6.00E16       1.19E05      1
  1994ZAB/KIR827-845   CCl2FC(O)O2NO2 → CCl2FC(O)OO· + NO2  310 - 323   6.00E16       1.18E05      1
  1994ZAB/KIR827-845   CCl3C(O)O2NO2 → CCl3C(O)OO· + NO2  305 - 315   3.20E17       1.21E05      1
  1994ZAB/KIR827-845   CCl3C(O)O2NO2 → CCl3C(O)OO· + NO2  305 - 315   1.60E17       1.21E05      1
  1994ZAB/KIR827-845   CCl3C(O)O2NO2 → CCl3C(O)OO· + NO2  305 - 315   0.40       9.98E04      2
  1994ZAB/KIR827-845   CClF2CH2OONO2 → NO2 + CF2ClCH2OO·  250 - 260   2.00E16       9.06E04      1
  1994ZAB/KIR827-845   CCl2FCH2OONO2 → NO2 + CFCl2CH2OO(·)  250 - 260   2.00E16       9.15E04      1
Search returned 10 records.