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Title: Thermal decomposition of CF3C(O)O2NO2, CClF2C(O)O2NO2, CCl2FC(O)O2NO2, and CCl3C(O)O2NO2
Journal: Int. J. Chem. Kinet.
Volume: 26
Page(s): 827 - 845
Year: 1994
Reference type: Journal article
Squib: 1994ZAB/KIR827-845
Reaction:
CCl2FCH2OONO2 → NO2 + CFCl2CH2OO(·)
Reaction order:
1
Temperature:
250 - 260
K
Pressure: 1.00 bar
Rate expression:
2.0x1016 [s-1] e-91459 [±5471 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Fourier transform (FTIR)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 250 | 1.56E-3 |
| 260 | 8.45E-3 |