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Author(s):   Zabel, F.; Kirchner, F.; Becker, K.H.
Title:   Thermal decomposition of CF3C(O)O2NO2, CClF2C(O)O2NO2, CCl2FC(O)O2NO2, and CCl3C(O)O2NO2
Journal:   Int. J. Chem. Kinet.
Volume:   26
Page(s):   827 - 845
Year:   1994
Reference type:   Journal article
Squib:   1994ZAB/KIR827-845

Reaction:   CCl3C(O)O2NO2 → CCl3C(O)OO· + NO2
Reaction order:   1
Temperature:   305 - 315 K
Pressure:  0.80 bar
Rate expression:   1.6x1017 [s-1] e-120560 [±4822 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
305 3.61E-4
315 1.63E-3