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Author(s):   Zabel, F.; Kirchner, F.; Becker, K.H.
Title:   Thermal decomposition of CF3C(O)O2NO2, CClF2C(O)O2NO2, CCl2FC(O)O2NO2, and CCl3C(O)O2NO2
Journal:   Int. J. Chem. Kinet.
Volume:   26
Page(s):   827 - 845
Year:   1994
Reference type:   Journal article
Squib:   1994ZAB/KIR827-845

Reaction:   CCl3C(O)O2NO2 → CCl3C(O)OO· + NO2
Reaction order:   2
Temperature:   305 - 315 K
Pressure:  2.79E-2 bar
Rate expression:   4.0x10-1 [cm3/molecule s] e-99774 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
305 3.28E-18
315 1.14E-17