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Accessibility information
Author(s):   Darwin, D.C.; Moore, C.B.
Title:   Reaction rate constants (295 K) for 3CH2 with H2S, SO2, and NO2: upper bounds for rate constants with less reactive partners
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   13467 - 13470
Year:   1995
Reference type:   Journal article
Squib:   1995DAR/MOO13467-13470

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1995DAR/MOO13467-13470   Acetone + ·CH2 → Products  295   <2.19E-14              2
  1995DAR/MOO13467-13470   Benzene + ·CH2 → Products  295   <1.10E-14              2
  1995DAR/MOO13467-13470   C2H6 + ·CH2 → Products  295   <9.00E-15              2
  1995DAR/MOO13467-13470   C2H4 + ·CH2 → Products  295   <8.00E-15              2
  1995DAR/MOO13467-13470   C2H2 + ·CH2 → Products  295   <1.40E-14              2
  1995DAR/MOO13467-13470   CH3Cl + ·CH2 → Products  295   <1.91E-14              2
  1995DAR/MOO13467-13470   CO2 + ·CH2CH2O + CO  295   <1.40E-14              2
  1995DAR/MOO13467-13470   H2C=C=O + ·CH2 → Products  295   <3.50E-13              2
  1995DAR/MOO13467-13470   CO + ·CH2 → Products  295   <7.51E-15              2
  1995DAR/MOO13467-13470   H2 + ·CH2·CH3 +   295   <6.91E-15              2
  1995DAR/MOO13467-13470   SO2 + ·CH2 → Products  295   4.90E-12              2
  1995DAR/MOO13467-13470   H2S + ·CH2 → Products  295   2.01E-12              2
  1995DAR/MOO13467-13470   N2O + ·CH2 → Products  295   <1.91E-14              2
  1995DAR/MOO13467-13470   NO2 + ·CH2 → Products  295   6.91E-11              2

Search returned 14 records.