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Accessibility information
Author(s):   Hsu, K.-J.; DeMore, W.B.
Title:   Rate constants and temperature dependences for the reactions of hydroxyl radical with several halogenated methanes, ethanes, and propanes by relative rate measurements
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   1235 - 1244
Year:   1995
Reference type:   Journal article
Squib:   1995HSU/DEM1235-1244

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1995HSU/DEM1235-1244   CH2F2 + ·OH → ·CHF2 + H2O  297 - 383   1.79E-12       1.29E04   9.88E-15  2
  1995HSU/DEM1235-1244   CH2F2 + ·OH → ·CHF2 + H2O  297 - 383   0.80       2303   0.32  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1995HSU/DEM1235-1244   CH3CHF2 + ·OH → Other Products + H2O  298 - 358   1.91E-12       1.01E04   3.18E-14  2
  1995HSU/DEM1235-1244   CH3CHF2 + ·OH → Other Products + H2O  298 - 358   0.64       -4980   4.78  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CHF2Cl + ·OH → ·CClF2 + H2O  298 - 366   7.11E-13       1.23E04   4.95E-15  2
  1995HSU/DEM1235-1244   CHF2Cl + ·OH → ·CClF2 + H2O  298 - 366   0.24       -2844   0.76  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CHF3 + ·OH → ·CF3 + H2O  298 - 383   6.39E-13       1.95E04   2.40E-16  2
  1995HSU/DEM1235-1244   CHF3 + ·OH → ·CF3 + H2O  298 - 383   1.14       5438   0.13  2
  Reference reaction:  C2F5H + ·OH → C2F5 + H2O 2
  1995HSU/DEM1235-1244   CF3CHCl2 + ·OH → H2O + CF3CCl2  298 - 359   6.39E-13       7566   3.02E-14  2
  1995HSU/DEM1235-1244   CF3CHCl2 + ·OH → H2O + CF3CCl2  298 - 359   0.28       -3035   0.95  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1995HSU/DEM1235-1244   C2H5F + ·OH → Other Products + H2O  285 - 364   1.00E-11       1.02E04   1.61E-13  2
  1995HSU/DEM1235-1244   C2H5F + ·OH → Other Products + H2O  285 - 364   1.16       1314   0.68  2
  Reference reaction:  C2H6 + ·OH → ·C2H5 + H2O 2
  1995HSU/DEM1235-1244   CCl2FCHClF + ·OH → H2O + CFCl2CFCl  294 - 362   7.11E-13       9645   1.45E-14  2
  1995HSU/DEM1235-1244   CCl2FCHClF + ·OH → H2O + CFCl2CFCl  294 - 362   0.31       -973   0.46  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1995HSU/DEM1235-1244   CH3CF3 + ·OH → CF3CH2 + H2O  298 - 403   1.30E-12       1.70E04   1.38E-15  2
  1995HSU/DEM1235-1244   CH3CF3 + ·OH → CF3CH2 + H2O  298 - 403   0.43       1854   0.20  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   1,1,1,2,3,3-Hexafluoropropane + ·OH → Other Products + H2O  298 - 380   1.10E-12       1.32E04   5.31E-15  2
  1995HSU/DEM1235-1244   1,1,1,2,3,3-Hexafluoropropane + ·OH → Other Products + H2O  298 - 380   0.36       -1921   0.78  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CF3CHFCF3 + ·OH → (CF3)2CF + H2O  296 - 398   4.90E-13       1.41E04   1.63E-15  2
  1995HSU/DEM1235-1244   CF3CHFCF3 + ·OH → (CF3)2CF + H2O  296 - 398   0.17       -973   0.25  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CH3F + ·OH → ·CH2F + H2O  298 - 363   2.19E-12       1.21E04   1.69E-14  2
  1995HSU/DEM1235-1244   CH3F + ·OH → ·CH2F + H2O  298 - 363   0.99       1447   0.55  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1995HSU/DEM1235-1244   Propane, 1,1,2,2,3-pentafluoro- + ·OH → Other Products + H2O  286 - 364   2.01E-12       1.38E04   7.65E-15  2
  1995HSU/DEM1235-1244   Propane, 1,1,2,2,3-pentafluoro- + ·OH → Other Products + H2O  286 - 364   0.67       -1364   1.16  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   Propane, 1,1,1,3,3,3-hexafluoro- + ·OH → H2O + (CF3)2CH·  298 - 367   7.01E-13       1.90E04   3.33E-16  2
  1995HSU/DEM1235-1244   Propane, 1,1,1,3,3,3-hexafluoro- + ·OH → H2O + (CF3)2CH·  298 - 367   1.26       4822   0.18  2
  Reference reaction:  C2F5H + ·OH → C2F5 + H2O 2
  1995HSU/DEM1235-1244   CHBrF2 + ·OH → H2O + CBrF2  283 - 368   9.60E-13       1.13E04   1.00E-14  2
  1995HSU/DEM1235-1244   CHBrF2 + ·OH → H2O + CBrF2  283 - 368   0.33       -3825   1.54  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CF3CHFCl + ·OH → CF3CFCl· + H2O  298 - 366   1.00E-12       1.21E04   7.72E-15  2
  1995HSU/DEM1235-1244   CF3CHFCl + ·OH → CF3CFCl· + H2O  298 - 366   0.35       -3051   1.20  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
Search returned 30 records.