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Accessibility information
Author(s):   Hsu, K.-J.; DeMore, W.B.
Title:   Rate constants and temperature dependences for the reactions of hydroxyl radical with several halogenated methanes, ethanes, and propanes by relative rate measurements
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   1235 - 1244
Year:   1995
Reference type:   Journal article
Squib:   1995HSU/DEM1235-1244

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1995HSU/DEM1235-1244   CH2F2 + ·OH → ·CHF2 + H2O  297 - 383   1.79E-12       1.29E04   9.88E-15  2
  1995HSU/DEM1235-1244   CH2F2 + ·OH → ·CHF2 + H2O  297 - 383   0.80       2303   0.32  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1995HSU/DEM1235-1244   CH3CHF2 + ·OH → Other Products + H2O  298 - 358   1.91E-12       1.01E04   3.18E-14  2
  1995HSU/DEM1235-1244   CH3CHF2 + ·OH → Other Products + H2O  298 - 358   0.64       -4980   4.78  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CHF2Cl + ·OH → ·CClF2 + H2O  298 - 366   7.11E-13       1.23E04   4.95E-15  2
  1995HSU/DEM1235-1244   CHF2Cl + ·OH → ·CClF2 + H2O  298 - 366   0.24       -2844   0.76  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CHF3 + ·OH → ·CF3 + H2O  298 - 383   6.39E-13       1.95E04   2.40E-16  2
  1995HSU/DEM1235-1244   CHF3 + ·OH → ·CF3 + H2O  298 - 383   1.14       5438   0.13  2
  Reference reaction:  C2F5H + ·OH → C2F5 + H2O 2
  1995HSU/DEM1235-1244   CF3CHCl2 + ·OH → H2O + CF3CCl2  298 - 359   6.39E-13       7566   3.02E-14  2
  1995HSU/DEM1235-1244   CF3CHCl2 + ·OH → H2O + CF3CCl2  298 - 359   0.28       -3035   0.95  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1995HSU/DEM1235-1244   C2H5F + ·OH → Other Products + H2O  285 - 364   1.00E-11       1.02E04   1.61E-13  2
  1995HSU/DEM1235-1244   C2H5F + ·OH → Other Products + H2O  285 - 364   1.16       1314   0.68  2
  Reference reaction:  C2H6 + ·OH → ·C2H5 + H2O 2
  1995HSU/DEM1235-1244   CCl2FCHClF + ·OH → H2O + CFCl2CFCl  294 - 362   7.11E-13       9645   1.45E-14  2
  1995HSU/DEM1235-1244   CCl2FCHClF + ·OH → H2O + CFCl2CFCl  294 - 362   0.31       -973   0.46  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1995HSU/DEM1235-1244   CH3CF3 + ·OH → CF3CH2 + H2O  298 - 403   1.30E-12       1.70E04   1.38E-15  2
  1995HSU/DEM1235-1244   CH3CF3 + ·OH → CF3CH2 + H2O  298 - 403   0.43       1854   0.20  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   1,1,1,2,3,3-Hexafluoropropane + ·OH → Other Products + H2O  298 - 380   1.10E-12       1.32E04   5.31E-15  2
  1995HSU/DEM1235-1244   1,1,1,2,3,3-Hexafluoropropane + ·OH → Other Products + H2O  298 - 380   0.36       -1921   0.78  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CF3CHFCF3 + ·OH → (CF3)2CF + H2O  296 - 398   4.90E-13       1.41E04   1.63E-15  2
  1995HSU/DEM1235-1244   CF3CHFCF3 + ·OH → (CF3)2CF + H2O  296 - 398   0.17       -973   0.25  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CH3F + ·OH → ·CH2F + H2O  298 - 363   2.19E-12       1.21E04   1.69E-14  2
  1995HSU/DEM1235-1244   CH3F + ·OH → ·CH2F + H2O  298 - 363   0.99       1447   0.55  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
  1995HSU/DEM1235-1244   Propane, 1,1,2,2,3-pentafluoro- + ·OH → Other Products + H2O  286 - 364   2.01E-12       1.38E04   7.65E-15  2
  1995HSU/DEM1235-1244   Propane, 1,1,2,2,3-pentafluoro- + ·OH → Other Products + H2O  286 - 364   0.67       -1364   1.16  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   Propane, 1,1,1,3,3,3-hexafluoro- + ·OH → H2O + (CF3)2CH·  298 - 367   7.01E-13       1.90E04   3.33E-16  2
  1995HSU/DEM1235-1244   Propane, 1,1,1,3,3,3-hexafluoro- + ·OH → H2O + (CF3)2CH·  298 - 367   1.26       4822   0.18  2
  Reference reaction:  C2F5H + ·OH → C2F5 + H2O 2
  1995HSU/DEM1235-1244   CHBrF2 + ·OH → H2O + CBrF2  283 - 368   9.60E-13       1.13E04   1.00E-14  2
  1995HSU/DEM1235-1244   CHBrF2 + ·OH → H2O + CBrF2  283 - 368   0.33       -3825   1.54  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
  1995HSU/DEM1235-1244   CF3CHFCl + ·OH → CF3CFCl· + H2O  298 - 366   1.00E-12       1.21E04   7.72E-15  2
  1995HSU/DEM1235-1244   CF3CHFCl + ·OH → CF3CFCl· + H2O  298 - 366   0.35       -3051   1.20  2
  Reference reaction:  CH4 + ·OH → ·CH3 + H2O 2
Search returned 30 records.