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Author(s):   Hsu, K.-J.; DeMore, W.B.
Title:   Rate constants and temperature dependences for the reactions of hydroxyl radical with several halogenated methanes, ethanes, and propanes by relative rate measurements
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   1235 - 1244
Year:   1995
Reference type:   Journal article
Squib:   1995HSU/DEM1235-1244

Reaction:   CH2F2 + ·OH·CHF2 + H2O
Reaction order:   2
Reference reaction:   CH3CHF2 + ·OH → Other Products + H2O
Temperature:   297 - 383 K
Pressure:  1.01 bar
Rate expression:   1.79x10-12 [cm3/molecule s] e-12887 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
297 9.71E-15
300 1.02E-14
325 1.52E-14
350 2.14E-14
375 2.87E-14
383 3.13E-14