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Author(s):   Hsu, K.-J.; DeMore, W.B.
Title:   Rate constants and temperature dependences for the reactions of hydroxyl radical with several halogenated methanes, ethanes, and propanes by relative rate measurements
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   1235 - 1244
Year:   1995
Reference type:   Journal article
Squib:   1995HSU/DEM1235-1244

Reaction:   Propane, 1,1,1,3,3,3-hexafluoro- + ·OHH2O + (CF3)2CH·
Reaction order:   2
Reference reaction:   C2F5H + ·OHC2F5 + H2O
Reference reaction order:   2
Temperature:   298 - 367 K
Pressure:  1.01 bar
Rate expression:   1.26±4.2x10-1 e-4822 [±915 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 1.80E-1
300 1.82E-1
325 2.12E-1
350 2.40E-1
367 2.59E-1