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Accessibility information
Author(s):   Kalra, B.L.; Afriyie, Y.; Brandt, B.; Lewis, D.K.; Baldwin, J.E.
Title:   Kinetics of the thermal isomerizations of gaseous cycloheptene and cyclooctene
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   8142 - 8146
Year:   1995
Reference type:   Journal article
Squib:   1995KAL/AFR8142-8146

Reaction:   (Z)-Cycloheptene → Products
Reaction order:   1
Temperature:   1040 - 1260 K
Pressure:  0.11 - 0.15 bar
Rate expression:   2.51x1015 [s-1] e-292669 [±14633 J/mole]/RT
Uncertainty:   10.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1040 5.02E0
1050 6.93E0
1075 1.51E1
1100 3.18E1
1125 6.47E1
1150 1.28E2
1175 2.45E2
1200 4.57E2
1225 8.32E2
1250 1.48E3
1260 1.85E3