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Accessibility information
Author(s):   Kalra, B.L.; Afriyie, Y.; Brandt, B.; Lewis, D.K.; Baldwin, J.E.
Title:   Kinetics of the thermal isomerizations of gaseous cycloheptene and cyclooctene
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   8142 - 8146
Year:   1995
Reference type:   Journal article
Squib:   1995KAL/AFR8142-8146

Reaction:   (Z)-CyclohepteneCyclopentane, ethenyl-
Reaction order:   1
Temperature:   1040 - 1260 K
Pressure:  0.11 - 0.15 bar
Rate expression:   1.26x1015 [s-1] e-291838 [±14550 J/mole]/RT
Uncertainty:   10.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1040 2.77E0
1050 3.82E0
1075 8.32E0
1100 1.75E1
1125 3.55E1
1150 7.00E1
1175 1.34E2
1200 2.50E2
1225 4.53E2
1250 8.04E2
1260 1.01E3