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Accessibility information
Author(s):   Kalra, B.L.; Afriyie, Y.; Brandt, B.; Lewis, D.K.; Baldwin, J.E.
Title:   Kinetics of the thermal isomerizations of gaseous cycloheptene and cyclooctene
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   8142 - 8146
Year:   1995
Reference type:   Journal article
Squib:   1995KAL/AFR8142-8146

Reaction:   (Z)-CycloocteneCyclohexane, ethenyl-
Reaction order:   1
Temperature:   645 - 1110 K
Pressure:  0.14 - 0.19 bar
Rate expression:   1.58x1015 [s-1] e-269389 [±5388 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
645 2.42E-7
650 3.55E-7
675 2.25E-6
700 1.25E-5
725 6.17E-5
750 2.74E-4
775 1.10E-3
800 4.07E-3
825 1.39E-2
850 4.41E-2
875 1.31E-1
900 3.66E-1
925 9.70E-1
950 2.44E0
975 5.84E0
1000 1.34E1
1025 2.96E1
1050 6.27E1
1075 1.29E2
1100 2.55E2
1110 3.33E2