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Accessibility information
Author(s):   Kalra, B.L.; Afriyie, Y.; Brandt, B.; Lewis, D.K.; Baldwin, J.E.
Title:   Kinetics of the thermal isomerizations of gaseous cycloheptene and cyclooctene
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   8142 - 8146
Year:   1995
Reference type:   Journal article
Squib:   1995KAL/AFR8142-8146

Reaction:   (Z)-Cyclooctene1,7-Octadiene
Reaction order:   1
Temperature:   610 - 1090 K
Pressure:  0.14 - 0.19 bar
Rate expression:   6.31x1013 [s-1] e-228648 [±2286 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
610 1.66E-6
625 4.91E-6
650 2.67E-5
675 1.28E-4
700 5.48E-4
725 2.12E-3
750 7.51E-3
775 2.45E-2
800 7.43E-2
825 2.11E-1
850 5.61E-1
875 1.42E0
900 3.39E0
925 7.74E0
950 1.69E1
975 3.55E1
1000 7.19E1
1025 1.41E2
1050 2.66E2
1075 4.90E2
1090 6.97E2