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Accessibility information
Author(s):   Linder, D.P.; Page, M.
Title:   Ab initio determination of the energy barriers and rate constants for HOBO+HF→’FBO+H2O and OBBO+HF→’FBO+HBO
Journal:   J. Chem. Phys.
Volume:   103
Page(s):   8538 - 8543
Year:   1995
Reference type:   Journal article
Squib:   1995LIN/PAG8538-8543

Reaction:   HF + BHO2H2O + OBF
Reaction order:   2
Temperature:   900 - 3000 K
Rate expression:   1.21x10-15 [cm3/molecule s] (T/298 K)2.71 e-98942 [J/mole]/RT
Category:  Theory
Data type:   Ab initio

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
900 4.37E-20
1000 2.18E-19
1100 8.34E-19
1200 2.60E-18
1300 6.93E-18
1400 1.63E-17
1500 3.46E-17
1600 6.77E-17
1700 1.24E-16
1800 2.13E-16
1900 3.49E-16
2000 5.48E-16
2100 8.31E-16
2200 1.22E-15
2300 1.74E-15
2400 2.42E-15
2500 3.30E-15
2600 4.41E-15
2700 5.78E-15
2800 7.47E-15
2900 9.51E-15
3000 1.20E-14