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Author(s):   Mogelberg, T.E.; Feilberg, A.; Biessing, A.M.B.; Sehested, J.; Bilde, M.; Wallington, T.J.; Nielsen, O.J.
Title:   Atmospheric chemistry of HFC-236cb: spectrokinetic investigation of the CF3CF2CFHO2 radical, its reaction with NO and NO2, and the fate of the CF3CF2CFHO radical
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   17386 - 17393
Year:   1995
Reference type:   Journal article
Squib:   1995MOG/FEI17386-17393

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1995MOG/FEI17386-17393   CF3CF2CFHOO(.) + CF3CF2CFHOO(.) → Products  296   5.20E-12              2
  1995MOG/FEI17386-17393   CF3CF2CFHOO(.) + NO → CF3CF2CFHO(.) + NO2  296   >8.00E-12              2
  1995MOG/FEI17386-17393   CF3CF2CFHOO(.) + NO2 → CF3CF2CFHOONO2  296   6.29E-12              2
  1995MOG/FEI17386-17393   Propane, 1,1,1,2,2,3-hexafluoro- + ·F → CF3CF2CHF· + HF  296   1.30E-12              2
  1995MOG/FEI17386-17393   Propane, 1,1,1,2,2,3-hexafluoro- + ·F → CF3CF2CHF· + HF  296   0.30              2
  Reference reaction:  CH2F2 + ·F·CHF2 + HF 2
  1995MOG/FEI17386-17393   Propane, 1,1,1,2,2,3-hexafluoro- + ·Cl → CF3CF2CHF· + HCl  296   1.50E-15              2
  1995MOG/FEI17386-17393   Propane, 1,1,1,2,2,3-hexafluoro- + ·Cl → CF3CF2CHF· + HCl  296   0.25              2
  Reference reaction:  CD4 + ·ClCD3 + DCl 2

Search returned 7 records.