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Author(s):   Russell, D.K.; Davidson, I.M.T.; Ellis, A.M.; Mills, G.p.; Pennington, M.; Povey, I.M.; Raynor, J.B.; Saydam, S.; Workman, A.D.
Title:   Mechanisms of pyrolysis of tricarbonylcyclopentadienylmanganese and tricarbonyl(methylcyclopentadienyl)manganese
Journal:   Organometallics
Volume:   14
Page(s):   3717 - 3723
Year:   1995
Reference type:   Journal article
Squib:   1995RUS/DAV3717-3723

Reaction:   Manganese, carbonyl [(1,2,3,4,5-eta)-1-methyl-2,4-cyclopentadien-1-yl]- → CO + Manganese(1+), [(1,2,3,4,5-eta)-1-methyl-2,4-cyclopentadien-1-yl]-
Reaction order:   1
Temperature:   523 - 723 K
Rate expression:   3.16x1015 [s-1] e-149660 [J/mole]/RT
Uncertainty:   2.0
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
523 3.57E0
525 4.07E0
550 1.93E1
575 8.02E1
600 2.96E2
625 9.82E2
650 2.97E3
675 8.29E3
700 2.15E4
723 4.87E4