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Author(s):   Tsang, W.; Walker, J.A.
Title:   Hydrogen-atom-induced decomposition of trichloroethylene at high temperatures
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   3156 - 3161
Year:   1995
Reference type:   Journal article
Squib:   1995TSA/WAL3156-3161

Reaction:   C2HCl3 + CH2=CCl2 + Cl
Reaction order:   2
Reference reaction:   1,3,5-Trimethylbenzene + 1,3-Dimethylbenzene + ·CH3
Reference reaction order:   2
Temperature:   970 - 1140 K
Rate expression:   8.89x10-1±2.0x10-1 e6785 [±1422 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
970 2.06E0
975 2.05E0
1000 2.01E0
1025 1.97E0
1050 1.93E0
1075 1.90E0
1100 1.87E0
1125 1.84E0
1140 1.82E0