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Accessibility information
Author(s):   Wallington, T.J.; Schneider, W.F.; Mogelberg, T.E.; Nielsen, O.J.; Sehested, J.
Title:   Atmospheric chemistry of FCOx radicals: kinetic and mechanistic study of the FC(O)O2 + NO2 reaction
Journal:   Int. J. Chem. Kinet.
Volume:   27
Page(s):   391 - 402
Year:   1995
Reference type:   Journal article
Squib:   1995WAL/SCH391-402

Reaction:   FC(O)OONO2NO2 + FC(O)OO
Reaction order:   1
Temperature:   293 - 3040 K
Pressure:  0.13 - 0.93 bar
Rate expression:   6.0x1016 [s-1] e-118066 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Ultrasonics
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
293 5.38E-5
300 1.67E-4
400 2.29E1
500 2.78E4
600 3.16E6
700 9.29E7
800 1.17E9
900 8.43E9
1000 4.08E10
1100 1.49E11
1200 4.36E11
1300 1.08E12
1400 2.36E12
1500 4.64E12
1600 8.39E12
1700 1.41E13
1800 2.25E13
1900 3.41E13
2000 4.95E13
2100 6.94E13
2200 9.44E13
2300 1.25E14
2400 1.62E14
2500 2.05E14
2600 2.55E14
2700 3.12E14
2800 3.76E14
2900 4.48E14
3000 5.28E14
3040 5.62E14