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Accessibility information
Author(s):   Wu, F.; Carr, R.W.
Title:   Observation of the CFCl2CH2O radical in the flash photolysis of CFCl2CH3 in the presence of O2. Kinetics of the reactions of Cl and ClO with CFCl2CH2O2 and CH3CFClO2
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   3128 - 3136
Year:   1995
Reference type:   Journal article
Squib:   1995WU/CAR3128-3136

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1995WU/CAR3128-3136   CH3CFClOO· + ClO → CH3CFClO + ClOO  253 - 321   4.50E-12           4.50E-12  2
  1995WU/CAR3128-3136   CH3CFClOO· + ·Cl → CH3CFClO + ClO  253 - 321   8.00E-11       5371   9.16E-12  2
  1995WU/CAR3128-3136   ClO + CFCl2CH2OO(·) → CFCl2CH2O· + ClOO  253 - 321   5.99E-12           5.99E-12  2
  1995WU/CAR3128-3136   ·Cl + CFCl2CH2OO(·) → CFCl2CH2O· + ClO  253 - 321   6.09E-10       6477   4.46E-11  2

Search returned 4 records.