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Author(s):   Wu, F.; Carr, R.W.
Title:   Observation of the CFCl2CH2O radical in the flash photolysis of CFCl2CH3 in the presence of O2. Kinetics of the reactions of Cl and ClO with CFCl2CH2O2 and CH3CFClO2
Journal:   J. Phys. Chem.
Volume:   99
Page(s):   3128 - 3136
Year:   1995
Reference type:   Journal article
Squib:   1995WU/CAR3128-3136

Reaction:   CH3CFClOO· + ·Cl → CH3CFClO + ClO
Reaction order:   2
Temperature:   253 - 321 K
Pressure:  5.33E-3 - 8.00E-2 bar
Rate expression:   8.0x10-11 [±2.99x10-11 cm3/molecule s] e-5371 [±591 J/mole]/RT
Bath gas:   N2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
253 6.23E-12
275 7.64E-12
300 9.29E-12
321 1.07E-11