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Author(s):   Bednarek, G.; Arguello, G.A.; Zellner, R.
Title:   FTIR-spectroscopic study of reactions of FCO and FC(O)OO radicals in the presence of O2 and NO2
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   100
Page(s):   445 - 454
Year:   1996
Reference type:   Journal article
Squib:   1996BED/ARG445-454

Reaction:   FC(O)OOOC(O)F → FC(O)O· + FC(O)OO
Reaction order:   1
Temperature:   250 K
Pressure:  1.01 bar
Rate expression:   6.0x10-4 [s-1]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

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