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Author(s):   Brownsword, R.A.; Herbert, L.B.; Smith, I.W.M.; Stewart, D.W.A.
Title:   Pressure and temperature dependence of the rate constants for the association reactions of CH radicals with CO and N2 between 202 and 584 K
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   92
Page(s):   1087 - 1094
Year:   1996
Reference type:   Journal article
Squib:   1996BRO/HER1087-1094

Reaction:   CO + ·CH → Products
Reaction order:   3
Temperature:   202 - 584 K
Pressure:  5.33E-3 - 0.53 bar
Rate expression:   4.11x10-30 [cm6/molecule2 s] (T/298 K)-2.50
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
202 1.09E-29
225 8.29E-30
250 6.37E-30
275 5.02E-30
300 4.04E-30
325 3.31E-30
350 2.75E-30
375 2.31E-30
400 1.97E-30
425 1.69E-30
450 1.47E-30
475 1.28E-30
500 1.13E-30
525 9.97E-31
550 8.88E-31
575 7.94E-31
584 7.64E-31