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Accessibility information
Author(s):   Campbell, M.L.
Title:   Kinetic study of the reaction of Ru(a 5F5) with N2O and O2 from 296 to 623 K
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   92
Page(s):   4377 - 4384
Year:   1996
Reference type:   Journal article
Squib:   1996CAM4377-4384

Reaction:   Ru + N2ON2 + RuO
Reaction order:   2
Temperature:   296 - 623 K
Pressure:  6.67E-3 - 0.27 bar
Rate expression:   4.05x10-34 [cm3/molecule s] (T/298 K)-3.95
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 4.16E-34
300 3.95E-34
325 2.88E-34
350 2.15E-34
375 1.63E-34
400 1.27E-34
425 9.97E-35
450 7.95E-35
475 6.42E-35
500 5.25E-35
525 4.33E-35
550 3.60E-35
575 3.02E-35
600 2.55E-35
623 2.20E-35