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Accessibility information
Author(s):   Czarnowski, I.
Title:   Kinetics and mechanism of the thermal gas-phase reaction between trifluoromethylhypofluorite, CF3OF, and tetrachloroethene
Journal:   Int. J. Chem. Kinet.
Volume:   28
Page(s):   489 - 495
Year:   1996
Reference type:   Journal article
Squib:   1996CZA489-495

Reaction:   C2Cl4 + CF3OF → ·CCl2CFCl2 + CF3O
Reaction order:   2
Temperature:   313 - 343 K
Pressure:  2.21E-2 - 0.12 bar
Rate expression:   5.25x10-14 [±9.96x10-15 cm3/molecule s] e-63606 [±7001 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
313 1.27E-24
325 3.14E-24
343 1.08E-23