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Accessibility information
Author(s):   DeMore, W.B.
Title:   Experimental and estimated rate constants for the reactions of hydroxyl radicals with several halocarbons
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   5813 - 5820
Year:   1996
Reference type:   Journal article
Squib:   1996DEM5813-5820

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1996DEM5813-5820   CH2Br2 + ·OHH2O + CHBr2  293 - 375   1.91E-12       6951   1.16E-13  2
  1996DEM5813-5820   CH2Br2 + ·OHH2O + CHBr2  293 - 375   0.84       -1206   1.36  2
  Reference reaction:  CH2Cl2 + ·OHCHCl2 + H2O 2
  1996DEM5813-5820   CH2ClBr + ·OHH2O + ·CHBrCl  293 - 376   1.79E-12       7533   8.58E-14  2
  1996DEM5813-5820   CH2ClBr + ·OHH2O + ·CHBrCl  293 - 376   0.83       -624   1.07  2
  Reference reaction:  CH2Cl2 + ·OHCHCl2 + H2O 2
  1996DEM5813-5820   CHBr3 + ·OHCBr3 + H2O  298 - 366   1.60E-12       5912   1.47E-13  2
  1996DEM5813-5820   CHBr3 + ·OHCBr3 + H2O  298 - 366   0.73       -2295   1.84  2
  Reference reaction:  CH2Cl2 + ·OHCHCl2 + H2O 2
  1996DEM5813-5820   CF2BrCHFCl + ·OH → CF2BrCFCl· + H2O  315 - 372   9.30E-13       1.04E04      2
  1996DEM5813-5820   CF2BrCHFCl + ·OH → CF2BrCFCl· + H2O  315 - 372   0.52       -2478      2
  Reference reaction:  CH3CCl3 + ·OHH2O + CCl3CH2 2
  1996DEM5813-5820   Ethane, 1,2,2-trichloro-1,1-difluoro- + ·OHH2O + CCl2CF2Cl  303 - 363   0.50       66.52      2
  Reference reaction:  CH2Cl2 + ·OHCHCl2 + H2O 2
  1996DEM5813-5820   Ethane, 1,2,2-trichloro-1,1-difluoro- + ·OHH2O + CCl2CF2Cl  303 - 363   8.30E-13       7425      2
  1996DEM5813-5820   Ethane, 1,2,2-trichloro-1,1-difluoro- + ·OHH2O + CCl2CF2Cl  313 - 371   0.96       -948      2
  Reference reaction:  CF3CHCl2 + ·OHH2O + CF3CCl2 2
  1996DEM5813-5820   CH3F + ·OH·CH2F + H2O  308 - 398   4.40E-12       1.38E04      2
  1996DEM5813-5820   CH3F + ·OH·CH2F + H2O  308 - 398   0.97       1297      2
  Reference reaction:  CH3Cl + ·OH·CH2Cl + H2O 2
  1996DEM5813-5820   CH2FCl + ·OHH2O + ·CClFH  293 - 371   1.79E-12       9977   3.20E-14  2
  1996DEM5813-5820   CH2FCl + ·OHH2O + ·CClFH  293 - 371   0.81       1796   0.39  2
  Reference reaction:  CH2Cl2 + ·OHCHCl2 + H2O 2

Search returned 15 records.