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Accessibility information
Author(s):   DeMore, W.B.
Title:   Experimental and estimated rate constants for the reactions of hydroxyl radicals with several halocarbons
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   5813 - 5820
Year:   1996
Reference type:   Journal article
Squib:   1996DEM5813-5820

Reaction:   CF2BrCHFCl + ·OH → CF2BrCFCl· + H2O
Reaction order:   2
Reference reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Temperature:   315 - 372 K
Pressure:  1.01 bar
Rate expression:   9.3x10-13 [cm3/molecule s] e-10393 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
315 1.76E-14
325 1.99E-14
350 2.61E-14
372 3.23E-14