Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   DeMore, W.B.
Title:   Experimental and estimated rate constants for the reactions of hydroxyl radicals with several halocarbons
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   5813 - 5820
Year:   1996
Reference type:   Journal article
Squib:   1996DEM5813-5820

Reaction:   CF2BrCHFCl + ·OH → CF2BrCFCl· + H2O
Reaction order:   2
Reference reaction:   CH3CCl3 + ·OHH2O + CCl3CH2
Temperature:   315 - 372 K
Pressure:  1.01 bar
Rate expression:   9.3x10-13 [cm3/molecule s] e-10393 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
315 1.76E-14
325 1.99E-14
350 2.61E-14
372 3.23E-14