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Accessibility information
Author(s):   Fontijn, A.; Bajaj, P.N.
Title:   Kinetics of the Sn(3Po) reactions with CO2 and O2 over wide temperature ranges
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   7085 - 7089
Year:   1996
Reference type:   Journal article
Squib:   1996FON/BAJ7085-7089

Reaction:   CO2 + SnCO + SnO
Reaction order:   2
Temperature:   690 - 1600 K
Pressure:  7.91E-3 - 8.00E-2 bar
Rate expression:   2.31x10-10 [cm3/molecule s] e-75662 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
690 4.32E-16
700 5.22E-16
750 1.24E-15
800 2.65E-15
850 5.17E-15
900 9.38E-15
950 1.60E-14
1000 2.58E-14
1050 3.98E-14
1100 5.89E-14
1150 8.45E-14
1200 1.17E-13
1250 1.59E-13
1300 2.10E-13
1350 2.73E-13
1400 3.47E-13
1450 4.34E-13
1500 5.35E-13
1550 6.51E-13
1600 7.82E-13