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Author(s):   Huybrechts, G.; Narmon, M.; Van Mele, B.
Title:   The pyrolysis of CCl4 and C2Cl6 in the gas phase. Mechanistic modeling by thermodynamic and kinetic parameter estimation
Journal:   Int. J. Chem. Kinet.
Volume:   28
Page(s):   27 - 36
Year:   1996
Reference type:   Journal article
Squib:   1996HUY/NAR27-36

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1996HUY/NAR27-36   CCl4·CCl3 + Cl  300 - 800   9.13E-05       2.84E05      2
  1996HUY/NAR27-36   CCl4 + Cl·CCl3 + Cl2  300 - 800   9.55E-11       6.49E04      2
  1996HUY/NAR27-36   CCl3CCl3 + ·CCl3CCl4 + C2Cl5  300 - 800   1.35E-12       5.90E04      2
  1996HUY/NAR27-36   CCl3CCl3 + Cl → C2Cl5 + Cl2  300 - 800   2.19E-10       7.23E04      2
  1996HUY/NAR27-36   ·CCl3 + ·CCl3CCl3CCl3  300 - 800   7.77E-12              2
  1996HUY/NAR27-36   C2Cl5C2Cl4 + Cl  300 - 800   1.86E-08       6.24E04      2
  1996HUY/NAR27-36   C2Cl5 + ClCCl3CCl3  300 - 800   4.07E-11              2
  1996HUY/NAR27-36   C2Cl5 + ClC2Cl4 + Cl2  300 - 800   4.07E-11              2
  1996HUY/NAR27-36   Cl2Cl + Cl  300 - 800   1.41E-08       2.34E05      2

Search returned 9 records.