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Author(s):   Kumaran, S.S.; Su, M.-C.; Lim, K.P.; Michael, J.V.; Wagner, A.F.; Harding, L.B.
Title:   Ab initio calculations and three different applications of unimolecular rate theory for the dissociations of CCl4, CFCl3, CF2Cl2, and CF3Cl
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   7541 - 7549
Year:   1996
Reference type:   Journal article
Squib:   1996KUM/SU7541-7549

Reaction:   CCl4·CCl3 + Cl
Reaction order:   1
Temperature:   1050 - 2200 K
Rate expression:   1.4x1016 [s-1] e-269904 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 5.24E2
1100 2.14E3
1200 2.50E4
1300 2.00E5
1400 1.19E6
1500 5.59E6
1600 2.16E7
1700 7.13E7
1800 2.06E8
1900 5.32E8
2000 1.25E9
2100 2.71E9
2200 5.47E9