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Accessibility information
Author(s):   Kumaran, S.S.; Su, M.-C.; Lim, K.P.; Michael, J.V.; Wagner, A.F.; Harding, L.B.
Title:   Ab initio calculations and three different applications of unimolecular rate theory for the dissociations of CCl4, CFCl3, CF2Cl2, and CF3Cl
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   7541 - 7549
Year:   1996
Reference type:   Journal article
Squib:   1996KUM/SU7541-7549

Reaction:   CF3Cl·CF3 + ·Cl
Reaction order:   1
Temperature:   1050 - 2200 K
Rate expression:   7.4x1016 [s-1] (T/298 K)-1.25 e-372147 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 4.71E-3
1100 3.08E-2
1200 8.21E-1
1300 1.31E1
1400 1.40E2
1500 1.08E3
1600 6.42E3
1700 3.09E4
1800 1.24E5
1900 4.29E5
2000 1.31E6
2100 3.57E6
2200 8.88E6