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Accessibility information
Author(s):   Li, S.C.; Williams, F.A.
Title:   Experimental and numerical studies of two-stage methanol flames
Journal:   Symp. Int. Combust. Proc.
Volume:   26
Page(s):   1017 - 1024
Year:   1996
Reference type:   Journal article
Squib:   1996LI/WIL1017-1024

Reaction:   CH3OH + ·OH(·)CH2OH + H2O
Reaction order:   2
Reference reaction:   CH3OH + ·OHCH3 + H2O
Reference reaction order:   2
Temperature:   300 - 2500 K
Rate expression:   2.3x10-1 e9811 [J/mole]/RT
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
300 1.17E1
400 4.39E0
500 2.44E0
600 1.64E0
700 1.24E0
800 1.01E0
900 8.53E-1
1000 7.49E-1
1100 6.72E-1
1200 6.15E-1
1300 5.70E-1
1400 5.34E-1
1500 5.05E-1
1600 4.81E-1
1700 4.60E-1
1800 4.43E-1
1900 4.28E-1
2000 4.15E-1
2100 4.03E-1
2200 3.93E-1
2300 3.84E-1
2400 3.76E-1
2500 3.69E-1