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Accessibility information
Author(s):   Li, S.C.; Williams, F.A.
Title:   Experimental and numerical studies of two-stage methanol flames
Journal:   Symp. Int. Combust. Proc.
Volume:   26
Page(s):   1017 - 1024
Year:   1996
Reference type:   Journal article
Squib:   1996LI/WIL1017-1024

Reaction:   CH3OH + H2 + (·)CH2OH
Reaction order:   2
Reference reaction:   CH3OH + H2 + CH3
Reference reaction order:   2
Temperature:   300 - 2500 K
Rate expression:   4.3x10-1 e5604 [J/mole]/RT
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
300 4.07E0
400 2.32E0
500 1.66E0
600 1.32E0
700 1.13E0
800 9.99E-1
900 9.09E-1
1000 8.44E-1
1100 7.94E-1
1200 7.54E-1
1300 7.22E-1
1400 6.96E-1
1500 6.74E-1
1600 6.55E-1
1700 6.39E-1
1800 6.25E-1
1900 6.13E-1
2000 6.02E-1
2100 5.93E-1
2200 5.84E-1
2300 5.76E-1
2400 5.69E-1
2500 5.63E-1