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Accessibility information
Author(s):   Ma, A.; Sun, L-P.; Wang, Y-X.; Liu, C-B.; Deng, C-H.
Title:   A theoretical study of the decompositions of CF3CO and CF3C(O) radicals
Journal:   Gaodeng Xuexiao Huaxue Xuebao
Volume:   17
Page(s):   777 - 780
Year:   1996
Reference type:   Journal article
Squib:   1996MA/SUN777-780

Reaction:   CF3C(O)CO + ·CF3
Reaction order:   1
Temperature:   100 - 1500 K
Rate expression:   9.02x1014 [s-1] e-57536 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
100 7.98E-16
200 8.48E-1
300 8.66E4
400 2.77E7
500 8.80E8
600 8.84E9
700 4.59E10
800 1.58E11
900 4.13E11
1000 8.91E11
1100 1.67E12
1200 2.82E12
1300 4.40E12
1400 6.44E12
1500 8.95E12