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Author(s):   McDoniel, J.B.; Holmes, B.E.
Title:   Substituent effects and threshold energeis for the unimolecular elimination of HCl (DCl) and HF (DF) from chemically activated CFCl2CH3 and CFCl2CD3
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   3044 - 3050
Year:   1996
Reference type:   Journal article
Squib:   1996MCD/HOL3044-3050

Reaction:   ·CCl2F + ·CCl2FCFCl3 + ·CClF
Reaction order:   2
Reference reaction:   ·CCl2F + ·CCl2FCFCl2CFCl2
Reference reaction order:   2
Temperature:   398 K
Pressure:  4.00E-5 - 8.00E-2 bar
Rate expression:   7.0x10-2±3.0x10-2
Rate constant is an upper limit.
Bath gas:   SF6
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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