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Author(s):   Mogelberg, T.E.; Sehested, J.; Bilde, M.; Wallington, T.J.; Nielsen, O.J.
Title:   Atmospheric chemistry of CF3CFHCF3 (HFC-227ea): spectrokinetic investigation of the CF3CFO2.CF3 radical, its reactions with NO and NO2, and fate of the CF3CFO.CF3
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   8882 - 8889
Year:   1996
Reference type:   Journal article
Squib:   1996MOG/SEH8882-8889

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1996MOG/SEH8882-8889   CF3CHFCF3 + ·F(CF3)2CF + HF  295   0.98              2
  Reference reaction:  CHF3 + ·F → Products 2
  1996MOG/SEH8882-8889   CF3CHFCF3 + ·F(CF3)2CF + HF  296   1.84E-13              2
  1996MOG/SEH8882-8889   CF3CHFCF3 + ·F(CF3)2CF + HF  296   0.15              2
  Reference reaction:  CF3CHCl2 + ·FHF + CF3CCl2 2
  1996MOG/SEH8882-8889   CF3CHFCF3 + ·F(CF3)2CF + HF  295   1.50E-13              2
  1996MOG/SEH8882-8889   CF3CHFCF3 + ·F(CF3)2CF + HF  295   0.46              2
  Reference reaction:  C2F5H + ·F → Products 2
  1996MOG/SEH8882-8889   CF3CHFCF3 + ·Cl(CF3)2CF + HCl  295   4.50E-17              2
  1996MOG/SEH8882-8889   CF3CHFCF3 + ·Cl(CF3)2CF + HCl  295   0.18              2
  Reference reaction:  C2F5H + ·Cl → Products 2
  1996MOG/SEH8882-8889   CF3CHFCF3 + ·Cl(CF3)2CF + HCl  295   0.13              2
  Reference reaction:  C2F5CF2H + ·Cl → Products 2
  1996MOG/SEH8882-8889   NO + CF3CFOO(.)CF3NO2 + (CF3)2CFO(·)  296   2.09E-11              2
  1996MOG/SEH8882-8889   NO2 + CF3CFOO(.)CF3 → (CF3)2CFOONO2  296   4.80E-12              2
  1996MOG/SEH8882-8889   CF3CFOO(.)CF3 + CF3CFOO(.)CF3 → Products  296   1.79E-12              2

Search returned 11 records.