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Accessibility information
Author(s):   Plane, J.M.C.; Rollason, R.J.
Title:   A kinetic study of the reactions of Fe(a 5D) and Fe+(a 6D) with N2O over the temperature range 294-850 K
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   92
Page(s):   4371 - 4376
Year:   1996
Reference type:   Journal article
Squib:   1996PLA/ROL4371-4376

Reaction:   Fe + N2OFeO + N2
Reaction order:   2
Temperature:   487 - 850 K
Rate expression:   2.31x10-10 [±1.83x10-10 cm3/molecule s] e-49388 [±2960 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
487 1.16E-15
500 1.60E-15
525 2.82E-15
550 4.71E-15
575 7.53E-15
600 1.16E-14
625 1.72E-14
650 2.48E-14
675 3.48E-14
700 4.76E-14
725 6.38E-14
750 8.39E-14
775 1.08E-13
800 1.38E-13
825 1.72E-13
850 2.13E-13