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Author(s):   Swihart, M.T.; Carr, R.W.
Title:   Pulsed laser powered homogeneous pyrolysis for reaction kinetics studies: probe laser measurement of reaction time and temperature
Journal:   Int. J. Chem. Kinet.
Volume:   28
Page(s):   817 - 828
Year:   1996
Reference type:   Journal article
Squib:   1996SWI/CAR817-828

Reaction:   CH3COOC2H5CH3C(O)OH + C2H4
Reaction order:   1
Temperature:   960 - 1160 K
Pressure:  0.13 bar
Rate expression:   1.0x1012 [s-1] e-199547 [±17959 J/mole]/RT
Uncertainty:   10.0
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography
Comments:   Experiments were carried out with the pulsed laser powered homogeneous pyrolysis technique.

The authors do not report the exact temperature range of their experiments. The stated temperature range was derived from the data shown in Figure 7 of the paper and is approximate.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
960 1.39E1
975 2.04E1
1000 3.78E1
1025 6.78E1
1050 1.18E2
1075 2.01E2
1100 3.35E2
1125 5.43E2
1150 8.64E2
1160 1.03E3