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Author(s):   Vinckier, C.; Vanhees, I.; Sengupta, D.; Nguyen, M.T.
Title:   Kinetic study in a microwave-induced plasma afterglow of the Cu(2S) atom reaction with CH3Cl in the temperature range 389-853 K
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   8302 - 8307
Year:   1996
Reference type:   Journal article
Squib:   1996VIN/VAN8302-8307

Reaction:   CH3Cl + Cu·CH3 + CuCl
Reaction order:   2
Temperature:   389 - 853 K
Rate expression:   1.73x10-11 [±4.48x10-12 cm3/molecule s] e-34671 [±1039 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
389 3.82E-16
400 5.13E-16
425 9.46E-16
450 1.63E-15
475 2.66E-15
500 4.12E-15
525 6.13E-15
550 8.80E-15
575 1.22E-14
600 1.66E-14
625 2.19E-14
650 2.83E-14
675 3.58E-14
700 4.47E-14
725 5.49E-14
750 6.65E-14
775 7.95E-14
800 9.41E-14
825 1.10E-13
850 1.28E-13
853 1.30E-13