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Accessibility information
Author(s):   Volman, D.H.
Title:   Photochemistry of the gaseous hydrogen peroxide-carbonmonoxide system. IV. Survey of the rate constant and reaction profile for the HO2 + CO →’ CO2 + OH reaction
Journal:   Photochem. Photobiol.
Volume:   100
Page(s):   1 - 3
Year:   1996
Reference type:   Journal article
Squib:   1996VOL1-3

Reaction:   CO + HO2CO2 + ·OH
Reaction order:   2
Temperature:   250 - 800 K
Rate expression:   5.96x10-11 [cm3/molecule s] (T/298 K)0.50 e-95616 [J/mole]/RT
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
250 5.75E-31
300 1.35E-27
350 3.47E-25
400 2.26E-23
450 5.84E-22
500 7.92E-21
550 6.73E-20
600 4.01E-19
650 1.82E-18
700 6.70E-18
750 2.07E-17
800 5.58E-17