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Accessibility information
Author(s):   von Gersum, S.; Roth, P.
Title:   Oxidation of fullerene C60 behind shock waves: tunable diode laser measurements of CO and CO2
Journal:   Infrared Phys. Technol.
Volume:   37
Page(s):   167 - 171
Year:   1996
Reference type:   Journal article
Squib:   1996VON/ROT167-171

Reaction:   [5,6]-Fullerene-C60 → Products
Reaction order:   2
Temperature:   1660 - 2700 K
Pressure:  1.52 - 2.64 bar
Rate expression:   1.66x10-10 [cm3/molecule s] e-187076 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV emission

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1660 2.16E-16
1700 2.97E-16
1800 6.19E-16
1900 1.19E-15
2000 2.16E-15
2100 3.69E-15
2200 6.01E-15
2300 9.37E-15
2400 1.41E-14
2500 2.05E-14
2600 2.90E-14
2700 3.99E-14