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Author(s):   Berry, R.J.; Ehlers, C.J.; Burgess, D.R., Jr.; Zachariah, M.R.; Marshall, P.
Title:   A computational study of the reactions of atomic hydrogen with fluoromethanes: kinetics and product channels
Journal:   Chem. Phys. Lett.
Volume:   269
Page(s):   107 - 116
Year:   1997
Reference type:   Journal article
Squib:   1997BER/EHL107-116

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1997BER/EHL107-116   CH4 + H2 + ·CH3  298 - 2500   9.58E-12   1.97   5.55E04   1.76E-21  2
  1997BER/EHL107-116   CH2F2 + CH3F + ·F  298 - 2500   7.79E-20   1.61   2.14E05   2.74E-57  2
  1997BER/EHL107-116   CH2F2 + H2 + ·CHF2  298 - 2500   4.30E-14   2.69   5.16E04   3.83E-23  2
  1997BER/EHL107-116   CH2F2 + ·CH2F + HF  298 - 2500   1.55E-11   1.73   1.48E05   1.78E-37  2
  1997BER/EHL107-116   CHF3 + CH2F2 + ·F  298 - 2500   6.53E-12   1.60   2.64E05   4.13E-58  2
  1997BER/EHL107-116   CHF3 + H2 + ·CF3  298 - 2500   1.23E-13   2.74   4.09E04   8.30E-21  2
  1997BER/EHL107-116   CHF3 + ·CHF2 + HF  298 - 2500   2.71E-11   1.65   1.65E05   2.70E-40  2
  1997BER/EHL107-116   CF4 + CHF3 + ·F  298 - 2500   5.88E-12   1.45   2.66E05   1.36E-58  2
  1997BER/EHL107-116   CF4 + ·CF3 + HF  298 - 2500   4.13E-11   1.58   1.73E05   2.01E-41  2
  1997BER/EHL107-116   CH3F + CH4 + ·F  298 - 2500   4.52E-12   1.61   1.60E05   3.37E-40  2
  1997BER/EHL107-116   CH3F + H2 + ·CH2F  298 - 2500   7.64E-12   1.96   4.48E04   1.07E-19  2
  1997BER/EHL107-116   CH3F + ·CH3 + HF  298 - 2500   6.87E-12   1.77   1.30E05   1.27E-34  2

Search returned 12 records.