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Author(s):   Bilde, M.; Sehested, J.; Nielsen, O.J.; Wallington, T.J.; Meagher, R.J.; McIntosh, M.E.; Piety, C.A.; Nicovich, J.M.; Wine, P.H.
Title:   Kinetics and mechanism of the gas phase reaction of atomic chlorine with CH2ICI at 206-432 K
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   8035 - 8041
Year:   1997
Reference type:   Journal article
Squib:   1997BIL/SEH8035-8041

Reaction:   ·CH2Cl + O2 → CH2ClO2
Reaction order:   2
Reference reaction:   ·CH2Cl + Cl2CH2Cl2 + Cl
Temperature:   295 K
Pressure:  1.33E-3 - 1.07 bar
Rate expression:   3.3x10-12 [±2.99x10-13 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is high pressure limit
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

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