Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Caralp, F.; Rayez, M-T.; Forst, W.; Bourbon, C.; Brioukov, M.; Devolder, P.
Title:   Kinetic study of the pressure dependence of the reaction CF3O + NO2 at 298 K. Rate constant measurements (P=0.5-9 Torr) and competition between association (CF3ONO2) and disproportionation (CF2O + FNO2) channels
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   93
Page(s):   3751 - 3756
Year:   1997
Reference type:   Journal article
Squib:   1997CAR/RAY3751-3756

Reaction:   NO2 + CF3OCOF2 + NO2F
Reaction order:   2
Temperature:   298 K
Pressure:  1.33E-4 - 4.00E-4 bar
Rate expression:   3.2x10-12 [cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   High or low pressure extrapolation
Pressure dependence:   Rate constant is low pressure limit
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.