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Author(s):   Caralp, F.; Rayez, M-T.; Forst, W.; Bourbon, C.; Brioukov, M.; Devolder, P.
Title:   Kinetic study of the pressure dependence of the reaction CF3O + NO2 at 298 K. Rate constant measurements (P=0.5-9 Torr) and competition between association (CF3ONO2) and disproportionation (CF2O + FNO2) channels
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   93
Page(s):   3751 - 3756
Year:   1997
Reference type:   Journal article
Squib:   1997CAR/RAY3751-3756

Reaction:   NO2 + CF3OCF3ONO2
Reaction order:   2
Temperature:   298 K
Pressure:  6.67E-4 - 1.20E-2 bar
Rate expression:   1.65x10-11 [±1.99x10-12 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   High or low pressure extrapolation
Pressure dependence:   Rate constant is high pressure limit
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

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