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Author(s):   De Silva, K.M.N.; Husain, D.
Title:   Bromine atom-abstraction reactions at elevated temperatures by ground state atomic rubidium, Rb(52S1/2), investigated by time-resolved laser induced fluorescence (Rb(52P3/2-52S1/2); <lambda> = 780 nm)
Journal:   J. Photochem. Photobiol. A
Volume:   111
Page(s):   1 - 7
Year:   1997
Reference type:   Journal article
Squib:   1997DES/HUS1-7

Reaction:   CH3Br + Rb·CH3 + RbBr
Reaction order:   2
Temperature:   875 K
Pressure:  1.67E-2 - 8.00E-2 bar
Rate expression:   2.01x10-11 [±9.96x10-13 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

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