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Accessibility information
Author(s):   Domingo, L.R.; Andres, J.; Moliner, V.; Safont, V.S.
Title:   Theoretical study of the gas phase decomposition of glycolic, lactic, and 2-hydroxyisobutyric acids
Journal:   J. Am. Chem. Soc.
Volume:   119
Page(s):   6415 - 6422
Year:   1997
Reference type:   Journal article
Squib:   1997DOM/AND6415-6422

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1997DOM/AND6415-6422   Propanoic acid, 2-hydroxy- → Products  613   1.13E-04              1
  1997DOM/AND6415-6422   Propanoic acid, 2-hydroxy-CH3CHO + CO + H2O  613   2.21E-06              1
  1997DOM/AND6415-6422   Propanoic acid, 2-hydroxy-H2O + Oxiranone, methyl-  613   1.10E-04              1
  1997DOM/AND6415-6422   Propanoic acid, 2-hydroxy-H2O + Oxiranone, methyl-  613   5.14E-07              1
  1997DOM/AND6415-6422   HOCH2COOH → Products  613   4.60E-05              1
  1997DOM/AND6415-6422   HOCH2COOHCH2O + CO + H2O  613   1.86E-06              1
  1997DOM/AND6415-6422   HOCH2COOHH2O + Oxiranone  612   4.41E-05              1
  1997DOM/AND6415-6422   HOCH2COOHH2O + Oxiranone  613   1.86E-10              1
  1997DOM/AND6415-6422   (CH3)2COHCOOH → Products  613   0.02              1
  1997DOM/AND6415-6422   (CH3)2COHCOOHH2O + Oxiranone, dimethyl-  613   0.02              1
  1997DOM/AND6415-6422   (CH3)2COHCOOHH2O + Oxiranone, dimethyl-  613   2.38E-03              1
  1997DOM/AND6415-6422   (CH3)2COHCOOHH2O + Oxiranone, dimethyl-  613   4.14E-05              1
  1997DOM/AND6415-6422   Oxiranone, dimethyl- → Acetone + CO  613   1050              1
  1997DOM/AND6415-6422   Oxiranone → CH2O + CO  613   619              1
  1997DOM/AND6415-6422   Oxiranone, methyl- → CH3CHO + CO  613   998              1

Search returned 15 records.