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Accessibility information
Author(s):   Kiefer, J.H.; Sathyanarayana, R.
Title:   Vibrational relaxation and dissociation in the perfluoromethyl halides, CF3Cl, CF3Br, and CF3I
Journal:   Int. J. Chem. Kinet.
Volume:   29
Page(s):   705 - 716
Year:   1997
Reference type:   Journal article
Squib:   1997KIE/SAT705-716

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1997KIE/SAT705-716   CF3Br·CF3 + Br·  1600 - 2500   6.31E-09       1.92E05      2
  1997KIE/SAT705-716   CF3Br·CF3 + Br·  1640 - 2570   62.44   -8.00   3.22E05      2
  1997KIE/SAT705-716   CF3Cl·CF3 + ·Cl  1800 - 3000   1.15E-08       2.35E05      2
  1997KIE/SAT705-716   CF3Cl·CF3 + ·Cl  1810 - 3060   1.15E-08       2.35E05      2
  1997KIE/SAT705-716   CF3Cl·CF3 + ·Cl  1810 - 3060   2756   -8.50   4.00E05      2
  1997KIE/SAT705-716   CF3I·CF3 + I  1270 - 2090   2.42   -7.50   2.38E05      2

Search returned 6 records.