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Accessibility information
Author(s):   Kiefer, J.H.; Sathyanarayana, R.
Title:   Vibrational relaxation and dissociation in the perfluoromethyl halides, CF3Cl, CF3Br, and CF3I
Journal:   Int. J. Chem. Kinet.
Volume:   29
Page(s):   705 - 716
Year:   1997
Reference type:   Journal article
Squib:   1997KIE/SAT705-716

Reaction:   CF3Cl·CF3 + ·Cl
Reaction order:   2
Temperature:   1800 - 3000 K
Pressure:  0.19 - 0.53 bar
Rate expression:   1.15x10-8 [cm3/molecule s] e-235300 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Laser schlieren

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1800 1.71E-15
1900 3.91E-15
2000 8.22E-15
2100 1.61E-14
2200 2.98E-14
2300 5.21E-14
2400 8.70E-14
2500 1.39E-13
2600 2.15E-13
2700 3.22E-13
2800 4.69E-13
2900 6.64E-13
3000 9.19E-13