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Author(s):   Kiefer, J.H.; Sathyanarayana, R.
Title:   Vibrational relaxation and dissociation in the perfluoromethyl halides, CF3Cl, CF3Br, and CF3I
Journal:   Int. J. Chem. Kinet.
Volume:   29
Page(s):   705 - 716
Year:   1997
Reference type:   Journal article
Squib:   1997KIE/SAT705-716

Reaction:   CF3Cl·CF3 + ·Cl
Reaction order:   2
Temperature:   1810 - 3060 K
Pressure:  0.40 bar
Rate expression:   2.76x103 [cm3/molecule s] (T/298 K)-8.50 e-399926 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is low pressure limit

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1810 1.74E-15
1900 4.05E-15
2000 9.28E-15
2100 1.93E-14
2200 3.68E-14
2300 6.52E-14
2400 1.08E-13
2500 1.71E-13
2600 2.57E-13
2700 3.70E-13
2800 5.13E-13
2900 6.88E-13
3000 8.96E-13
3060 1.04E-12